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Question

0.2175 g of the substance gave 0.5825g of BaSO4 by Carius method.Calculate the percentage of Sulphar.

A
36.78%
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B
39.52%
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C
32.86%
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D
41.85%
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Solution

The correct option is A 36.78%

Mass of organic compound = 0.2175

Mass of BaSO4 = 0.5825

% of S = 32/233 x mass of BaSO4/ mass of organic comp x 100

% S = 32/233 x 0.5825/0.2175 x 100 = 36.579


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