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Question

0.5 g of an organic compound on combustion produced some gaseous products which were passed into caustic potash solution. The increase in weight of potash solution was found to be 1.5 g. The percentage of carbon in the compound is nearly:

A
82%
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B
40%
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C
60%
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D
75%
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Solution

The correct option is A 82%
Since KOH is a solvent for CO2,

weight of CO2 evolved is 1.5 g =1.544=0.034 mol.

1 mole of CO2 contains 12 g of C.

0.034 moles will contain 12×0.034=0.408g of C.

Percentage of C in the compound is 0.4080.5×100=81.6%.

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