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Question

1.00 g of a non-electrolyte solute (molar mass 250g mol1) was dissolved in 51.2 g of benzene.If the freezing point depression constant Kf of benzene is 5.12 K kg mol1, the freezing point of benzene will be lowered by:

A
0.4 K
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B
0.3 K
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C
0.5 K
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D
0.2 K
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Solution

The correct option is A 0.4 K
ΔTf=Kf×W1×1000W2×M1whereW1=WeightofthesoluteW2=WeightofsolventM1=MolarmassofsoluteKf=FreezingpointdepressionconstantNow,ΔTf=5.12×1×100051.2×250ΔTf=0.4K

Hence, the correct option is A

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