1g of H2O changes from liquid to vapour phase at constant pressure at 1atm. The volume increases from 1ccto1671cc. The heat of vaporisation at this pressur is 540cal/g. The increase in internal energy of water is
A
2099J
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B
3000J
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C
992J
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D
2122J
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Solution
The correct option is A2099J Work done is given as- W=P(dV)=1.01×105(1671−1)×10−6=167J ΔQ = ΔU + ΔW or ΔU = ΔQ - ΔW =mL−167=(540×4.2)−167=2099J