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Question

1 g of H2O changes from liquid to vapour phase at constant pressure at 1 atm. The volume increases from 1 cc to 1671 cc. The heat of vaporisation at this pressur is 540 cal/g. The increase in internal energy of water is

A
2099J
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B
3000J
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C
992J
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D
2122J
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Solution

The correct option is A 2099J
Work done is given as-
W=P(dV)=1.01×105(16711)×106=167J
ΔQ = ΔU + ΔW
or
ΔU = ΔQ - ΔW
=mL167=(540×4.2)167=2099J

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