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Question

1 mole of MnO2−4 in neutral aqueous medium disproportionates to:

A
23 mole of MnO4 and 13 mole of MnO2.
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B
13 mole of MnO4 and 23 mole of MnO2.
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C
12 mole of Mn2O7 and 13 mole of MnO2.
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D
23 mole of Mn2O7 and 13 mole of MnO2.
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Solution

The correct option is A 23 mole of MnO4 and 13 mole of MnO2.
The oxidation state of Mn in MnO24, MnO4 and MnO2 are +6, +7 and +4 respectively.
Mn6+Mn7++1e
Mn6++2eMn4+

To balance the number of electrons, oxidation half reaction is multiplied with 2 and added to reduction half reaction.
3MnO242MnO4+MnO2
1 mole of MnO24 in neutral aqueous medium disproportionates to 23 mole of MnO4 and 13 mole of MnO2

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