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Elevation in Boiling Point

10 mL of C2H4...

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10 mL of C2H4 (g) is exploded with O2 (excess). The contraction in volume will be

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Q. A gaseous hydrocarbon (

12

ml) is exploded with an excess of oxygen. On cooling, the contraction in volume is

48

ml and there is further contraction of

48

ml in volume when passed through

C O_{2}

. The molecular formula of hydrocarbon is:

Q. 10 ml of a mixture of

C H_{4}, C_{2} H_{4}

C O_{2}

were exploded with excess of air. After explosion, there was contraction on cooling of 17 ml and after treatment with KOH, there was further reduction of 14 ml. What is the composition of the mixture?

Q. 10 ml mixture of

C O, C H_{4}

N_{2}

, exploded with an excess of oxygen, gave a contraction of 6.5 ml. There was a further contraction of 7ml when the residual gas was treated with

K O H

C O, C H_{4}

N_{2}

respectively, is :

Q. 20 ml of mixture of CO and

H_{2}

were mixed with excess of

O_{2}

and exploded and cooled . There was a volume contraction of 18 ml . All volume measurements corresponds to room temperature

(27^{0} C)

and one atmosphere pressure . Determine the volume ratio

V_{1} : V_{2}

H_{2}

in the original mixture.

Q. A gaseous mixture containing

C O

C H_{4}

N_{2}

gas has total volume of 40

m L

. This mixture is exploded with excess of oxygen, on cooling 30

m L

of contraction is observed and when this mixture is treated with aqueous

K O H

a further contraction of 30

m L

is observed. Find the composition of the mixture in

m L

.

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