100mL of PH3 on decomposition produced phosphorus and hydrogen. The change in volume is:
A
50ml increases
No worries! We‘ve got your back. Try BYJU‘S free classes today!
B
500ml decreases
No worries! We‘ve got your back. Try BYJU‘S free classes today!
C
900ml decreases
No worries! We‘ve got your back. Try BYJU‘S free classes today!
D
none of the above
Right on! Give the BNAT exam to get a 100% scholarship for BYJUS courses
Open in App
Solution
The correct option is D none of the above
The equation for the decomposition is:
4PH3(g)=P4(s)+6H2(g) (Elemental phosphorus exists as tetra atomic molecules). When the temperature and pressure remain the same, 4 ml of PH3 will give 6 ml of H2. (On applying Gay-Lussac's law ). Hence, 100 ml of PH3 will yield 150 ml of H2. Increase in volume = (150-100) ml = 50 ml. (The volume of solid phosphorus is negligible).