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Question

100 ml of water sample with initial pH 7.5 is titrated to pH=4.5 using 15 ml of 0.02 N H2SO4. The total alkalinity of water (in mgl as CaCO3). Rounded off to nearest integer is
  1. 150

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Solution

The correct option is A 150
1 ml of 0.2 N H2SO4 consumes 1 mg of alkalinity as CaCO3

Total alkalinity in 100 ml of water = 15 mg as CaCO3
Alkalinity in mgl as CaCO3=15100×103mgl as CaCO3=150mglas CaCO3

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