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Claisen Condensation

15. Acetic ac...

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15. Acetic acid undergoes dimerisation in benzene. What will be its van't Hoff factor valure if α is 100%?

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Q. What will be the value of Van't Hoff factor for ethanoic acid in benzene?

Acetic acid undergoes dimerisation, when dissolved in benzene (as shown in figure)
Molecular mass of acetic acid is found to be

120

Which among the following relation is correct?

α

= degree of association,

d

= observed vapour density,

D

= Theoretical vapour density).

Q. Acetic acid undergoes

25 %

dissociation and

30 %

association simultaneously. What will be the value of vant Hoff factor '

i

α

' is degree of dimerisation of

{C H}_{3} C O O H

in benzene, then van't Hoff factor '

i

' for circulation of colligative properties is:

Q. Acetic acid associates as dimers in benzene. What is the Van’t Hoff factor (i) if the degree of association of acetic acid is 50%?

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