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Question

150 mL of 0.0008 M ammonium sulphate is mixed with 50 mL of 0.04 M calcium nitrate. The ionic product of CaSO4 will be:
(KsP=2.4×105 for CaSO4)

A
<Ksp
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B
>Ksp
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C
Ksp
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D
None of these
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Solution

The correct option is B <Ksp
[Ca2+]=0.04 M×50 mL150 mL+50 mL=0.01 M

[SO24]=0.0008 M×150 mL150 mL+50 mL=0.0006 M

The ionic product of CaSO4 ,
Q=[Ca2+][SO24]

Q=0.01 M×0.0006 M

Q=6×106

The solubility product Ksp=2.4×105

Hence, Q<Ksp and no precipitate will be formed.

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