2 g of 109% oleum is diluted with water. To neutralize this solution completely, 44.49 ml of Ca(OH)2 solution is required. What is the molarity of Ca(OH)2 solution?
A
1.0 M
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B
0.1 M
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C
0.05 M
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D
0.5 M
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Solution
The correct option is D 0.5 M 2 g of 109% oleum =2×1.09=2.18 g of H2SO4 in dilute solution.
So, gm eq. of H2SO4=2.1898×2
Similarly, gm eq. of Ca(OH)2=44.49×10−3×M×2
Since, gmeq.ofH2SO4=gmeq.ofCa(OH)2
Therefore, 2.1898×2=44.49×10−3×M×2 ⇒M=0.5