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Question

20 mL of 0.2MNaOH(aq) solution is mixed with 35 mL of 0.1MNaOH(aq) solution and the resultant solution is diluted to 100 mL. 40 mL of this diluted solution reacted with 10% impure sample of oxalic acid (H2C2O4). The weight of impure sample is :

A
0.15 g
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B
0.135 g
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C
0.59 g
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D
none of the above
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Solution

The correct option is A 0.15 g
MNaOH (resultant) =20×0.2+35×0.1100=0.075M
Milli-equivalent of NaOH= Milli-equivalent of H2C2O4
Let weight of impure sample is x g.
40×0.075=x×0.9090×2×1000
x=0.15g
Hence, the weight of impure sample is 0.15 g.

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