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Question

25.0 g of FeSO4.7H2O was dissolved in water containing dilute H2SO4 and the volume was made up to 1.0 L. 25.0 mL of this solution required 20 mL of N10KMnO4 solution for complete oxidation. The percentage of FeSO4.7H2O in the acidic solution is :

A
78%
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B
98%
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C
89%
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D
79%
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Solution

The correct option is C 89%
Mili equivalents of FeSO4.7H2O in 25 ml = Milli equivalents of KMnO4 used =2 milli equivalents

Milli equivalents of FeSO4.7H2O in 1000 ml =80 milli equivalents.

Mass of FeSO4.7H2O in solution = 801×278×11000=22.24 g

% of FeSO4.7H2O=22.2425×100=88.89=89%

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