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Electrolysis

25 Equilibriu...

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25 Equilibrium concentration of PCl5 , PCl3 & Cl2 are 4M ,2M &2M resp. PCl5 --- PCl3 + Cl2. If volume of container is doubled then at new equilibrium, concentration of reactant & product will be

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Q. In the reaction

P C l_{5} ⇌ P C l_{3} + C l_{2}

the partial pressure of

P C l_{3}, C l_{2}

P C l_{5}

0.3, 0.2

0.6 a t m

respectively at equilibrium. If partial pressure of

P C l_{3}

C l_{2}

was increased twice, what will be the partial pressure of

P C l_{5}

a t m

at new equilibrium condition:

Q. An equilibrium mixture of

P {C l}_{5}, P {C l}_{3}

{C l}_{2}

at a certain temperature contians

0.5 \times 10^{- 3} M

P {C l}_{3}

1.5 \times 10^{- 2}

P {C l}_{3}

3 \times 10^{- 2} M

{C l}_{2}

. Calculate the equilibrium constant

K_{c}

for the reaction

P {C l}_{5} (g) ⇌ P {C l}_{3} (g) + {C l}_{2} (g)

Q. At a certain temperature, the reaction

P C l_{5} (g) ⇌ P C l_{3} (g) + C l_{2} (g)

has an equilibrium constant

K_{c} = 5.8 \times 10^{2}

. Calculate the equilibrium concentrations of

P C l_{5}, P C l_{3}

C l_{2}

P C l_{5}

is present initially,at a concentration of

0.160 M

Q. In the reaction

P C l_{5} ⇌ P C l_{3} + C l_{2}

the amount of each

P C l_{5}, P C l_{3}

C l_{2}

is 2 mole at equilibrium and total pressure is 3 atmosphere. The value of

k_{p}

Q. In the reaction,

P C l_{5} ⇌ P C l_{3} + C l_{2}

, the amount of each

P C l_{5}

P C l_{3}

C l_{2}

2

mole at equilibrium and total pressure is

3

atmosphere. The value of

K_{p}

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