25mL of a solution of barium hydroxide on titration with a 0.1M solution of HCl gave a titre value of 50mL. The molarity of the barium hydroxide solution is:
A
0.1 M
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B
0.3 M
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C
0.2 M
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D
0.2 M
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Solution
The correct option is A 0.1 M Let the molarity of Ba(OH)2 solution be kM. n-factor×M1V1=n-factor×M2V2 2×k×25=1×0.1×50
(Since n-factor of Ba(OH)2=2 and of HCl=1)
Molarity of Ba(OH)2 solution =0.1M