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Question

2CaSO4(s)2CaO(s)+2SO2(g)+O2(g),ΔH>0
If the above shown equilibrium is established by taking sufficient amount of CaSO4(s) in a closed container at 1600K, then which of the following is(are) correct? (Assume that solid CaSO4 is present in the container in each case)

A
Moles of CaO(s) will increase with the increase in temperature
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B
If the volume of the container is doubled at equilibrium, then partial pressure of SO2(g)will change at new equilibrium
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C
If the volume of the container is halved, then partial pressure of O2(g) at new equilibrium will remain same
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D
If two moles of He gas is added at constant pressure, then the moles of CaO(s) will increase
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Solution

The correct options are
A Moles of CaO(s) will increase with the increase in temperature
C If two moles of He gas is added at constant pressure, then the moles of CaO(s) will increase
D If the volume of the container is halved, then partial pressure of O2(g) at new equilibrium will remain same
A) As the reaction is endothermic, therefore it will go in the forward direction as the temperature increases. Hence, the moles of CaO will increase.
(C) With an increase or decrease in volume, the particle pressure of the gases will remain the same at equilibrium at a particular temperature.
(D) Due to the addition of inert gas at constant pressure, the reaction will proceed in the direction where more number of gaseous molecules are formed.

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