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Relating Translational KE and T

31. a moles o...

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31. a moles of pcl5 are heated in a closed container till equilibrium is established at a pressure of P atm. If b moles of pcl5 dissociate at equilibrium then what is the relation between a, b, kp, P

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Q. 'a' moles of

P C l_{5}

are heated in a closed container till equilibrium is established.

P C l_{5} (g) ⇋ P C l_{3} (g) + C l_{2} (g)

is maintianed at a pressure of P atm. If 'b' moles of

P C l_{5}

dissociates at equilibrium, then:

a

{P C l}_{5}

are heated in a closed container to equilibrate

P {C l}_{5 (g)} ⇌ P {C l}_{5 (g)} + {C l}_{2 (g)}

at a pressure of

P

x

{P C l}_{5}

dissociate at equilibrium, then:

a

P C l_{5}

are heated in a closed container to equilibriate

P C l_{5} (g) ⇌ P C l_{3} (g) + C l_{2} (g)

at a pressure of

P

x

P C l_{5}

dissociate at equilibrium, then:

P {C l}_{5}

is dissociating

50

250^{o} C

at a total pressure of

P

atm. If equilibrium constant is

K_{p}

, then which of the following relation is numerically correct?

Q. For gaseous decomposition of

P C l_{5}

in a closed vessel the degree of dissociation

α

, equilibrium pressure

P

K_{p}

are related as:

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Relating Translational KE and T

Standard XII Chemistry