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Byju's Answer
Standard XII
Chemistry
Amorphous Forms of Carbon
35. 5g of MnO...
Question
35. 5g of MnO2 on Rx with HCl forms 1.12L of Cl2 gas at S.T.P , The percentage impurity of MnO2 is ?
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Q.
10
g
of
M
n
O
2
on reaction with HCI forms
2.24
L
of
C
I
2
(
g
)
at NTP, the percentage impurity of
M
n
O
2
is:
M
n
O
2
+
4
H
C
I
→
M
n
C
I
2
+
C
I
2
+
2
H
2
O
Q.
8.7
g of pyrolusite (impure
M
n
O
2
) was heated with conc.
H
C
l
. The
C
l
2
gas evolved was passed through excess of
K
I
solution. The iodine gas evolved required
80
ml of
N
10
hypo solution. The percentage of
M
n
O
2
in pyrolusite will be :
Q.
Calculate the weight of
M
n
O
2
.
H
C
l
of specific gravity
1.2
g/mL and
5
%
by weight needed to produce
1.12
L
of
C
l
2
at STP by the reaction (as nearest integer).
M
n
O
2
+
4
H
C
l
→
M
n
C
l
2
+
3
H
2
O
+
C
l
2
Q.
If
x
g of
M
n
O
2
and the volume of
H
C
l
of specific gravity
1.2
g
m
L
−
3
and
5
%
by weight needed to produce
1.12
L
of
C
l
2
at STP by the reaction,
M
n
O
2
+
4
H
C
l
→
M
n
C
l
2
+
3
H
2
O
+
C
l
2
then value of 100X is
:
Q.
10
g of
M
n
O
2
on reaction with conc.
H
C
l
liberated
0.1
equivalent of
C
l
2
(molecular weight of
M
n
=
55
g/mol). Hence, percentage purity of
M
n
O
2
is
:
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