39. Acetylene on reaction with K2Cr2O7+H2SO4→ PRODUCT [O] 1)CH3CHO 2)CH3-CH2-CH3 3)CH3COOH 4)CH3OH

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2 C H_{3} - C H_{2} - O H H^{+} - -- \to 413 K C H_{3} - C H_{2} - O - C H_{2} - C H_{3} + H_{2} O

C H_{3} - O | | C - O - C H_{2} - C H_{3} + H - O \to (O = O_{18})

i) C H_{3} - C H_{2} - C H_{3} | C H - C H_{2} - O = C H_{2} - C H_{3}

i i) C H_{3} - C H_{2} - C H_{2} - O - C H_{3} | C | C H_{3} - C H_{3}

C H_{3} - C H_{2} - O - C H_{2} - C H_{3}

C H_{3} - C H_{3} | C = O

C H_{2} = P P h_{3} D M S O - --- \to C H_{3} - C H_{3} | C = C H_{2} + P h_{3} P = O

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