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Question

3Fe(s)+4H2O(g)Fe3O4(s)+4H2(g)+heat. Which of the following effects disturb the system from equilibrium?

A
Adding N2 gas at constant volume
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B
Adding some Fe powder
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C
Increasing Pressure
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D
Increasing temperature
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Solution

The correct option is B Adding some Fe powder
3Fe(s)+4H2O(g)Fe2O3(s)+4H2(g)
Pressure has no effect here as Δn=11=0
Δn=no. of product gas moles-no. of reactant gas moles
Adding Fe powder can disturb the system from equilibrium as reactants concentration increases, according to Le Chatelier's principle, equilibrium shifts towards products side.
Temperature does not have any effect because it is not mentioned whether the reaction is exothermic or endothermic. N2 does not change the equilibrium because there is no N2 in the reaction.

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