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Question

4.5 moles of each hydrogen and iodine are heated in a sealed 10-liter vessel. At equilibrium, 3 moles of hydrogen iodide was found.


The equilibrium constant for H2(g) + I2(g)2HI(g) is;

A
1
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B
10
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C
5
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D
0.33
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Solution

The correct option is A 1
The equilibrium reaction is H2(g)+I2(g)2HI(g).

The number of moles of various species present initially and at equilibrium is given in the following table.

H2 I2 HI
Initial 4.5 4.5 0
Change 1.5 1.5 3.0
Equilibrium 3.0 3.0 3.0
The expression for the equilibrium constant is Kc=[HI]2[H2][I2].
Substitute values in the above expression.

Kc=(3.010)2(3.010)×(3.010)=1

So, the correct option is A

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