4.8g of C (diamond) on complete combustion evolves 1584kJ of heat. The standard heat of formation of gaseous carbon is 725kJ/mol. The energy required for the process (i) C (graphite) →C (Gas) (ii) C (diamond) →C (gas) are:
A
725,727
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B
727,725
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C
725,723
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D
None of these
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Solution
The correct option is A725,727 C(graphite)→C(gas)
ΔH=725kJ/mol (given)
As graphite is thermodynamically more stable than diamond. Therefore, the heat required to convert graphite to gaseous should be more.