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Byju's Answer
Standard XII
Chemistry
Percentage Composition
4 g of hydrog...
Question
4
g of hydrogen
(
H
2
)
,
64
g of sulphur (S) and
44.8
L of
O
2
at STP react and form
H
2
S
O
4
. If
49
g of
H
2
S
O
4
is formed, then
%
yield is
?
A
25
%
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B
50
%
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C
75
%
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D
100
%
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Solution
The correct option is
B
50
%
H
2
+
S
+
2
O
2
⟶
H
2
S
O
4
2
g
32
g
64
g
|
|
|
98
g
44.8
L
The mole ratio is
H
:
S
:
O
=
1
:
1
:
2
Since
O
2
is limiting only
98
g
of
H
2
S
O
4
is formed.
Given
49
g
of
H
2
S
O
4
is formed.
So % yield=
49
98
×
100
=
50
% .
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0
Similar questions
Q.
Peroxydisulfuric acid
(
H
2
S
2
O
8
)
can be prepared by electrolytic oxidation of
H
2
S
O
4
as:
2
H
2
S
O
4
→
H
2
S
2
O
8
+
2
H
+
+
2
e
.
O
2
and
H
2
are by products. In such on electrolysis
0.87
g of
H
2
and
3.36
g
O
2
were generated at STP. Report the mass of
H
2
S
2
O
8
formed in decagram (write nearest integer).
Q.
Assertion (A):
109
%
H
2
S
O
4
represent a way to express concentration of industrial
H
2
S
O
4
.
Reason (R): It represents that
9
g
H
2
O
reacts with
40
g
S
O
3
to produce
49
g
H
2
S
O
4
in addition to
100
g
H
2
S
O
4
.
Q.
S
(
s
)
+
O
2
(
g
)
→
S
O
2
(
g
)
(
Y
i
e
l
d
=
80
%
)
S
O
2
(
g
)
+
C
l
2
+
2
H
2
O
→
H
2
S
O
4
+
2
H
C
l
H
2
S
O
4
+
B
a
C
l
2
→
B
a
S
O
4
+
2
H
C
l
(
Y
i
e
l
d
=
30
%
)
80
g
of Sulphur and
112
L
of oxygen at STP is burnt to form
S
O
2
,
which is oxidized by
56
L
of
C
l
2
gas at STP dissolved in water. This solution is treated with
B
a
C
l
2
solution. Calculate the moles of precipitate formed?
(Molar mass of barium =
137
g
/
m
o
l
)
Q.
S
+
O
2
→
S
O
2
(Yield = 80%)
S
O
2
+
C
l
2
+
2
H
2
O
→
H
2
S
O
4
+
2
H
C
l
(Yield = 60%)
H
2
S
O
4
+
B
a
C
l
2
→
B
a
S
O
4
+
2
H
C
l
(Yield = 30%)
8 g of Sulphur is burnt to form
S
O
2
, which is oxidized by
C
l
2
water. The solution is then treated with
B
a
C
l
2
solution. The amount of
B
a
S
O
4
precipitated is:
(Molar mass of Barium =
137
g/mol
)
Q.
Number of g moles of sulphur present in 49 g of
H
2
S
O
4
are:
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