4 moles of ammonia on reaction with 3 moles of calcium hypochlorite gives a salt (B), a gas (C) and water. Gas (C) on reaction with calcium gives compound (D) which on hydrolysis gives ammonia again . Identify (B), (C) and (D).
A
CaCl2,N2,Ca3N2
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B
Ca(OH)2,NH3,CaNH
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C
CaCl2,N2O5,Ca(NO3)2
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D
Ca(OH)2,NO2,CaN2
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Solution
The correct option is ACaCl2,N2,Ca3N2 4NH3(g)+3Ca(OCl)2→2N2(g)(C)+3CaCl2(B)+6H2ON2(g)(C)+3Ca→Ca3N2(D)Ca3N2(D)+6H2O→3Ca(OH)2+2NH3(g)