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Question

40 calories of heat is needed to raise the temperature of 1mol of an ideal monoatomic gas from 20C to 30C at a constant pressure. The amount of heat required to raise its temperature over the same interval at a constant volume (R=2cal/mol1K1) is :

A
20cal
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B
40cal
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C
60cal
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D
80cal
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Solution

The correct option is A 20cal
At constant pressure, the amount of heat required is

Q=nCpΔT

40=1×Cp×10

Thus, Cp=4

Now, γ=CpCv

γ for monoatomic gas =1.67
Thus, Cv=Cpγ=41.67=2.4

For a constant volume process,

Q=nCvΔT

Thus,

Q=1×2.4×10

Q=24 cal20 cal

Hence Option C

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