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Question

40 g of Ba(MnO4)2 (molecular weight =375 g/mol) sample containing some inert impurities in acidic medium is completely reacted with 125 mL of 33.6 V of H2O2. What is the percentage purity of the sample?

A
28.12
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B
70.31
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C
85
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D
None of the above
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Solution

The correct option is C 70.31
Normality of H2O2=Volume Strength of H2O25.6
NH2O2=33.65.6=6

Equivalents moles of H2O2=6×0.125=0.750 eq

Milli Equivalents of Ba(MnO4)2 reacted= Equivalents of H2O2 reacted.

Equivalent moles of Ba(MnO4)2=0.7510=0.075 eq

Weight of 0.075 equivalent moles =0.075×375 g

Purity of sample=0.075×37540×100=70.31%

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