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Formation of Enamines

50 A complex ...

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50 A complex containing K+, Pt(IV), and Cl- is 100%ionised giving i=3 thus,possible Complex is 1)K2[Pt Cl4] 2)K2[PtCl6] 3)K3[Pt Cl5] 4)K[Pt Cl3]

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Q. A complex containing K

^{+}

, Pt(IV) and Cl

^{-}

is 100% ionised giving

i =

3. Thus, the complex is :

[P T B r C l (N O_{2}) (N H_{3})] I

complex on ionization gives the ion ?

Q. Combination of

P t (I V), N H_{3}, C l^{-}, K^{+}

result in the formation of

x

complexes and one such complex is

[P t (N H_{3})_{6}] C l_{4}

x

[P t (N H_{3})_{6}] C l_{4}

complex gives :

P t C l_{4} .5 N H_{3}

shows a molar conductance of

402 {ohm}^{- 1} {cm}^{2} {mol}^{- 1}

in water and precipitates 3 moles of

A g C l

A g N O_{3}

solution. The formula of the complex is:

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Formation of Enamines

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