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Alcohols as Nucleophiles and Electrophiles

50. For the r...

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50. For the reaction, 2NO(g)+2H2(g) gives N2+2H2O(g) The rate expression can be written in the following ways: d(N2)/dt=k1(NO)(H2); d(H2O)/dt=k2(NO)(H2) -d(NO)/dt=k3(NO)(H2); -d(H2)/dt=k4(NO)(H2) The relationship between k1,k2,k3,k4 is

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Q. For the reaction,

2 N O (g) + 2 H_{2} (g) \to N_{2} (g) + 2 H_{2} O (g)

The rate expression can be written in following ways:

\frac{d [N_{2}]}{d t} = k_{1} [N O] [H_{2}]; \frac{d [H_{2} O]}{d t} = k_{2} [N O] [H_{2}]; \frac{- d [N O]}{d t} = k_{3} [N O] [H_{2}]; \frac{d [H_{2}]}{d t} = k_{4} [N O] [N_{2}]

The relationship between

k_{1}, k_{2}, k_{3}, k_{4}

Q. For the reaction,

2 N O (g) + 2 H_{2} (g) \to N_{2} (g) + 2 H_{2} O (g)

the rate expression can be written in the following ways:

{d t [N_{2}] / d t} = k_{1} [N O] [H_{2}]; {d [H_{2} O] / d t) = k [N O] [H_{2}];

{- d [N O] / d t} = k_{1}^{'} [N O] [H_{2}]; {- d [H_{2}] / d t} = k_{1}^{''} [N O] [H_{2}]

The relation ship between

k, k_{1}, k_{1}^{'}

k_{1}^{''}

Q. For the reaction

2 N O (g) + 2 H_{2} (g) \to N_{2} (g) + 2 H_{2} O (g)

The rate expression can be written in the following ways

\frac{d [N_{2}]}{d t} = k_{1} [N O] [H_{2}] \frac{d [H_{2} O]}{d t} = k [N O] [H_{2}] - \frac{d [N O]}{d t} = k_{1}^{'} [N O] [H_{2}] - \frac{d [H_{2}]}{d t} = k_{1}^{''} [N O] [H_{2}]

The relationship between

k, k_{1}, k_{1}^{'}

k_{1}^{''}

Q. For the reaction

2 N O (g) + 2 H_{2} (g) \to N_{2} (g) + 2 H_{2} O (g)

The rate expression can be written in the following ways

\frac{d [N_{2}]}{d t} = k_{1} [N O] [H_{2}] \frac{d [H_{2} O]}{d t} = k [N O] [H_{2}] - \frac{d [N O]}{d t} = k_{1}^{'} [N O] [H_{2}] - \frac{d [H_{2}]}{d t} = k_{1}^{''} [N O] [H_{2}]

The relationship betyween

k, k_{1}, k_{1}^{'}

k_{1}^{''}

Q. For the reaction,

N_{2} O_{5} ⟶ 2 N O_{2} + 1 / 2 O_{2}

,

- \frac{d [N_{2} O_{5}]}{d t} = k_{1} [N_{2} O_{5}]

\frac{d [N O_{2}]}{d t} = k_{2} [N_{2} O_{5}]

\frac{d [O_{2}]}{d t} = k_{3} [N_{2} O_{5}]

The relation in between

k_{1}, k_{2}

k_{3}

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