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Question

6 mol of a mixture containing same number of moles of NaNO3, NH4NO3, LiNO3, Ca(NO3)2,Pb(NO3)2 and AgNO3, was heated strongly. Total number of moles of O2(g) evolved is :

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Solution

6 compounds have 1 mole each.
NH4NO3 does not give O2.
2LiNO31 moleLi2O+2NO2+12O2(0.25 mole)
2Ca(NO3)2(1 mole)2CaO+4NO2+O2(0.5 mole)
2Pb(NO3)2(1 mole)2PbO+4NO2+O2(0.5 mole)
2Ag(NO3)2(1mole)2Ag+2NO2+O2(0.5 mole)
2Na(NO3)2(1 mole)Na2O+O2(0.5 mole)+NO+NO2
Total number of moles of O2 evolved =2.25

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