6 mol of a mixture containing same number of moles of NaNO3,NH4NO3,LiNO3,Ca(NO3)2,Pb(NO3)2 and AgNO3, was heated strongly. Total number of moles of O2(g) evolved is :
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Solution
6 compounds have 1 mole each. NH4NO3 does not give O2. 2LiNO31mole→Li2O+2NO2+12O2(0.25mole) 2Ca(NO3)2(1mole)→2CaO+4NO2+O2(0.5mole) 2Pb(NO3)2(1mole)→2PbO+4NO2+O2(0.5mole) 2Ag(NO3)2(1mole)→2Ag+2NO2+O2(0.5mole) 2Na(NO3)2(1mole)→Na2O+O2(0.5mole)+NO+NO2
Total number of moles of O2 evolved =2.25