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Question

6×103 mole K2Cr2O7 reacts completely with 9×103 mole Xn+ to give XO3 and Cr3+. The value of 'n' is?

A
1
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B
2
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C
3
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D
5
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Solution

The correct option is A 1
Cr2O27+14H++6e2Cr+3+7H2O
Xn++3H2OXO3+6H++(5n)e
It is given that 2 moles of K2Cr2O7 reacts with 3 moles of Xn+.So 2×number of electrons gained in reduction half reaction=3× number of electrons lost in oxidation half reaction
2×6=3×(5-n)
n=1

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