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Nucleophilic Substitution in Alkyl Halides

6. Which will...

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6. Which will undergo cationic hydrolysis? 1) NaCl 2) CH3COONa 3) (NH4)2SO4 4) H2CO3

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Q. Which will undergo cationic hydrolysis?

Q. Set -1 (solution) Set-2 (Hydrolysis type)
I) Aqueous solution of

A l C l_{3}

A)only anionic
II) Aqueous solution of

(N H_{4})_{2} C O_{3}

B) only cationic
III) Aqueous solution of NaCl C) Neither cationic nor anionic hydrolysis.
IV) Aqueous solution of

C H_{3} C O O N a

D) Both cationic and anionic hydrolysis.
The correct match is :

Q. In which of the following salts, cation does not undergo hydrolysis but anion undergoes hydrolysis?

Match List-1 with List-2.

List -1 List-2
A)

C H_{3} C O O N a + C H_{3} C O O H

1)Acidic due to cationic hydrolysis
B)

N H_{4} C l + N H_{4} O H

2)Basic due to anionic hydrolysis
C) aqueous

A l C l_{3}

3) Basic buffer solution
D) aqueous

N a_{2} C O_{3}

4)Acidic buffer solution

The pH of 0.1M aqueous solutions of NaCl, $C H_{3}$ COONa and $N H_{4}$ Cl will follow the order

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Nucleophilic Substitution in Alkyl Halides

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