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Introduction to Electrophilic Substitution

9. A: allyl c...

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9. A: allyl carbanion is more stable than nitromethyl carbanion. R: in nitro methyl carbanion only -I of NO2 is present while in allyl carbanion resonance is present

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Q. The false statements among the following are:
I. A primary carbocation is less stable than a tertiary carbocation.
II. A cyclopropyl methyl carbocation is less stable than allyl carbocation.
III. A tertiary free radical is more stable than a primary free radical.
IV. Isopropyl carbanion is more stable than ethyl carbanion.

Q. Assertion :The order of stability of carbanion are

(C_{6} H_{5})_{3} C^{-} > C_{6} H_{5} C H_{2}^{-} > a l l y l > C H_{3}^{-} > (C H_{3})_{2} C H^{-}

Reason: The stabiliby of carbanions is influenced by both resonance and inductive effects.

Q. Methyl carbanion is:

Most stable carbanion is

Q. Most stable carbanion is :-

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