Reduction of Amides,Oximes and Azides with LAH

Q.
What is sequence of reagent use to convert following

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1. $Ag\left[\right(N{H}_3{)}_2{]}^{+},H_2/Pd,B{r}_2/NaOH$
2. $H_2/Pd,B{r}_2/NaOH,\left[Ag\right(N{H}_3{)}_2{]}^{+}$
3. $H_2/Pd,\left[Ag\right(N{H}_3{)}_2{]}^{+},B{r}_2/NaOH$
4. $B{r}_2/NaOH,\left[Ag\right(N{H}_3)2{]}^{+},H_2/Pd$

Q. Find the correct final product among the following options?

1. $C{H}_{3}C{H}_{2}CON{H}_2$
2. $HCONHC{H}_{2}C{H}_3$
3. $C{H}_{3}C{H}_{2}CN$
4. $C{H}_{3}C{H}_{2}NC$

Q. $\mathrm{Ph}-C\equiv N\underset{\mathrm{Partial}\mathrm{Hydrolysis}}{\overset{H_3{O}^{+}}{\to }}\left(A\right)\stackrel{{\mathrm{Br}}_2+\mathrm{KOH}}{\to }\left(B\right)$
Product (B) is:

1. $Ph-C{H}_2-N{H}_2$
2. $Ph-OH$
3. $Ph-N{H}_2$
4. $Ph-C{H}_3$

Q. Identify the product D in the following reaction sequence:

1. 
2. 
3. 
4. 

Q. Which of the following reaction sequence(s) is/are suitable to convert acetone to methylamine?

1. $\stackrel{C{F}_{3}COOOH}{\to }\stackrel{N{H}_{2}N{H}_2/\Delta }{\to }\underset{\Delta }{\overset{NaN{O}_2/HCl}{\to }}\stackrel{H_3{O}^{+}}{\to }$
2. $\stackrel{I_2+NaOH}{\to }\stackrel{H^{+}/H_{2}O}{\to }\stackrel{PC{l}_5}{\to }\underset{\Delta }{\overset{N{H}_3}{\to }}\stackrel{B{r}_2+KOH}{\to }$
3. $\stackrel{I_2+NaOH}{\to }\stackrel{H^{+}}{\to }\underset{\Delta }{\overset{N{H}_3}{\to }}$
4. $\stackrel{I_2+NaOH}{\to }\stackrel{H^{+}}{\to }\underset{\Delta }{\overset{N{H}_3}{\to }}\stackrel{LiAl{H}_4}{\to }$

Q. What is ${}^{\prime }{X}^{\prime }$ in the following sequence of reactions?

1. $(C{H}_3{)}_{2}CHCOCl$
2. $C{H}_{3}C{H}_{2}CH\left(OH\right)C{H}_{2}Cl$
3. $C{H}_{3}C{H}_{2}C{H}_{2}COCl$
4. $ClC{H}_{2}C{H}_{2}C{H}_{2}CHO$

Q. Acetamide on treatment with $LiAl{H}_4$ forms:

1. ethyl amine
2. ethanimine
3. ethanoic acid
4. none of these

Q. Acetamide on treatment with______ forms ethylamine.

Q. How will you prepare ethylamine from the acetic acid ?

Q. Acetamide is treated separately with the following reagents. Which one of these would give methyl amine?

1. $P{Cl}_5$
2. $NaOH+{Br}_2$
3. soda lime
4. Hot conc. $H_2{SO}_4$