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Question

A 20 g chunk of dry ice is placed in an empty 0.75 L wire bottle tightly closed what would be the final pressure in the bottle after all CO2 has been evaporated and temperature reaches to 25°C?

A
15.8
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B
21.2
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C
12.5
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D
none
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Solution

The correct option is A 15.8
w = 20 g dry CO2
which will evaporate to develop pressure

m = 44, V = 0.75 L, P = ?, T = 298 K

PV=wmRT (as PV=nRT & n=wm)

P×0.75=204420/4450.0821×298

P = 14.228 atm

Pressure inside the bottle = P + atm pressure
=14.828+1=15.828 atm

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