A3B2 is a sparingly soluble salt of molar mass M (gmol−1) and solubility x g litre−1 . The ratio of the molar concentration of B3− to the solubility product of the salt is :
A
108X5M5
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B
1108M4X4
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C
154M4X4
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D
None of these
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Solution
The correct option is D154M4X4 Solubility S=xM A3B2(s)⇌3A2−(aq.)3S+2B3−(aq.)2S Ksp=(3S)2(2S)2=108S5 [B3−]Ksp=2S108S5=154M4x4