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Question

A calorimeter has mass 100g and specific heat 0.1 kcal/kg oC. It contains 250 gm of liquid at 30 oC having specific heat of 0.4 kcal/kg oC. If we drop a piece of ice of mass 10g at 0 oC. What will be the temperature of the mixture?

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Solution

1) Net Heat Change in this Process = 0
2) ice will be converted to water, then all will come at a equilibrium. Temperature.

Units are in SI system.
Steps:
1) Given,
Mass of Caloriemeter, m=100g=0.1kg
Specific Heat of Caloriemeter, S(C)=0.1units
Mass of liquid, m.=0.25kg
Specific Heat of Liquid, s(L)=0.4units
Mass of Ice, =0.01kg
Latent heat of fusion of Ice, L(f)=80units
Specific heat of water, S(w)=1units.

2) Heat due to fusion =mL
Heat due to change in T=msdel(T)

Let the final Equilibrium Temperature be T. Celsius.
Q(net)=Q(1)+Q(2)+Q(3)+Q(4)0=0.10.1(T30)+0.250.4(T30)+0.0180+10.01(T0)
Multiply by 100 on both sides,
0=T30+10(T30)+80+T
12T=250
T=20.83°C
Therefore, Final Temperature of mixture =20.83°C



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