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Question

A certain radioactive isotope ZXA(t1/2=10 day) decays to give Z4XA8. If 1 g atom of ZXA is kept in a sealed vessel, how much of He will accumulate in 20 days at STP?

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Solution

The nuclear reaction is:
AZXA4Z2Y+42He

Given, the half life period t1/2=10day, total time of decay T=20days, Initial amount of radioisotope N0=1gatoms
The number of half life periods in the total time of decay n=Tt1/2=2010=2

Amount left in 2 half lives =122=14gatom
Amount of X decayed in 2 half lives =(114)=34gatom

Amount of He formed=34gatom

(since 1 g-atom of X gives 1 g-atom of He)
Volume of He formed at STP =34×22400=16800mL

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