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Question

A certain weight of pure CaCO3 is made to react completely with 200 mL of a HCl solution to give 224 mL of CO2 gas at STP. The normality of the HCl is:

A
0.05 N
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B
0.1 N
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C
1.0 N
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D
0.2 N
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Solution

The correct option is B 0.1 N
The balanced reaction is as follows:

CaCO3+2HClCO2+CaCl2

224 mL of CO2 is 0.01 moles at STP.

Hence, number of moles of CaCO3 is 0.01.

Hence, 0.02 moles of HCl is needed for complete reaction.

Volume of HCl solution used is 200 mL.

For a monobasic acid, molarity = normality

Hence, Normality=molesvolume=0.020.2N

Normality=0.1N

Hence, the correct option is B

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