A closed vessel with rigid walls contain 1 mol of 23892U and 1 mol of air at 298 K. Considering complete decay of 23892U to 20682Pb, the ratio of the final pressure to the initial pressure of the system at 298 K is
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Solution
Initial moles of gases = 1 23892UInitial,1 moles→20682Pb+842He+6−1e∘Final,8 mole
Total gaseous moles after decomposition = 8 + 1 = 9 moles Ratio of pressures PfPi=nfni=9