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Question

A compound contains 4.07% hydrogen,24.27%carbon, 71.65%chlorine. its molecular mass is 98.96. What is its empirical and molecular formula?

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Solution


Element Percentage Atomic Mass Relative no. of atoms Simplest ratio Whole no. ratio
Carbon 24.27 12 24.2712= 2.022 2.0222.018=1 1
Hydrogen 4.07 1 4.071=4.07 4.072.018 2
Chlorine 71.65 35.5 71.6535.5=2.018 2.0182.018 1

Emperical formula = CH2Cl
Molecular formula = (CH2Cl)n

n=Molecular MassEmperical formula mass = 98.9649.5 = 2

Therefore, molecular formula = (CH2Cl)​2= C2H4Cl2

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