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Question

A compound mode up of element A and B crystallites in a cubic structure. Atoms A are present on the corners as well as face-centres, whereas atom B are present on the edge-centres as well as body-centre. What is the formula of the compound? Draw the structure of the unit cell.

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Solution

Effective number of atoms of A=18×8+12×6=4
Effective number of atoms of B=14×12+1=4
Formula =B4A4=BA
In the image A is red atoms and B is purple atoms.

990924_1069715_ans_afa6a24fa3cb4bebae85af15b7d31178.png

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