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Question

A compound of vanadium has a magnetic moment (μ) of 1.73 BM. If the vanadium ion in the compound is present as Vx+, then the value of x is ?

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Solution

Given,
μ=n(n+2)=1.73 BM
(where n is number of unpaired electrons)
n=1; 23V=1s22s22p63s23p64s23d3
For n=1, it must release 4 electrons, first two from 4sorbital and then next two electrons from 3rdorbital. So, x=4.

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