A compound of Xe and F is found to have 53.5% of Xe. What is oxidation number of Xe in this compound?
A
−4
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B
0
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C
+4
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D
+6
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Solution
The correct option is D+6 A compound of Xe and F is found to have 53.5% of Xe. 100 g of this compound will have 53.5 g of Xe and 46.5 g of F. The atomic masses of Xe and F are 131.2 g/mol and 19 g/mol respectively. The number of moles of Xe=53.5131.2=0.4 The number of moles of F=46.519=2.4 The mole ratio Xe:F=0.4:2.4=1:6 Molecular formula of the compound is XeF6 Let n be the oxidation number of Xe in XeF6 The oxidation number of F is −1 n+6(−1)=0 n−6=0 n=6 The oxidation number of Xe in XeF6 is +6