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Question

A conductivity cell filled with 0.02M AgNO3 gives at 25oC a resistance of 947 ohms. If the cells constant is 2.3cm1. What is the molar conductivity of 0.02M AgNO3 at 25oC?

A
121.43 Ω1cm2mol1
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B
101.4 Ω1cm2mol1
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C
111.4 Ω1cm2mol1
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D
None of the above
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Solution

The correct option is A 121.43 Ω1cm2mol1
conductivity (k) = 1R×lA (cell constant)
k=1947×2.3=239470
molar conductivity (dm) =239470×10000.02
(dm=k×1000m)=[121.43cm2mol1]

1199159_1035455_ans_bd10734216354fd7ab213a9aa858a8a5.jpeg

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