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Question

A cylinder filled with a movable piston contains liquid water in equilibrium with water vapour at 25°c . Which one of the following operations results in a decrease in equilibrium vapour pressure?
1. Moving piston downward a short distance
2. Removing a small amount of vapour
3. Removing a small amount of the liquid water
4. Dissolving salt in the water

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Solution

On dissolving salt in the water becoz on increasing the concentration, forward reaction decreases and hence results in decrease in the equilibrium vapour pressure.

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