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Question

A decapeptide (Mol. wt. 796) on complete hydrolysis gives glycine (Mol. wt. 75), alanine and phenylalanine.Glycine contributes 47.0% to the total weight of the hydrolysed products. The number of glycine units present in the decapeptide is

A
6
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B
6.0
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C
6.00
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Solution

Molecular weight of decapeptide = 796 g/mol
Total bonds to be hydrolysed ( 10-1 ) = 9 per molecule
Total weight of H2O added = 9 x 18= 162 g/mol
Total weight of hydrolysis products = 796 + 162 = 958 g
Total weight % ofglycine (given) = 47%

Total weight of glycine in product =958×47100 = 450 g
Molecular wetght of glycine = 75 g/mol
Number of glycine molecules = 45075=6

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