A diatomic gas molecule has translational, rotational and vibrational degree of freedom. The Cp/Cv is
Potential energy, U=f2nRT and CV=f2R
Where,
f is degree of freedom.
For diatomic gas, f=5
CV=52R
CP=CV+R=52R+R=72R
Specific heat ratio, γ=CpCv=75=1.4
Hence, specific heat ratio is 1.4