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Question

A flask of gaseous CCl4 was weighed at measured temperature and pressure. The flask was then flushed and filled with O2 at the same temperature and pressure. The weight of the CCl4 vapour will be:

A
five time as heavy as O2
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B
one fifth heavy as compared to O2
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C
same as that of O2
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D
twice as heavy as the O2
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Solution

The correct option is B five time as heavy as O2
Let V be the volume of flask
Since, the pressure and temperature are also same for both the gases, we will have same number of moles for each of them. Therefore, the ratio of weight will be the ratio of molecular weight of the gases.
Molecular weight of CCl4=154 g
Molecular weight of O2=32 g
Hence, the ratio comes out to be nearly 5.

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