A gas absorbs a photon of 355 nm and emits two wavelengths. If one of the emission is at 680 nm, the other is at:
743 nm
As we know, c=νλ ⇒ ν=cλ
By Planck's theory,
E=hν ⇒ E=hcλ
Now, using the law of conservation of energy: Absorbed Energy = Emitted Energy
hcλ = hcλ1 + hcλ2 ⇒1λ = 1λ1 + 1λ2
⇒1355 = 1680 + 1λ2
⇒ 1λ2 = 1355 - 1680
⇒ λ2 = 743 nm