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Question

A gas allowed to expand in a well insulated container against a constant external pressure of 2.5 atm from an initial volume of 2.50 L to a final volume of 4.50 L. The change in internal energy ΔU of the gas in joules will be

A
500 J
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B
505 J
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C
+505 J
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D
1136.25 J
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Solution

The correct option is B 505 J
W=PextΔV=2.5(4.502.50)
W=5 L atm=5×101.325 L. bar=506.625 J
ΔU=q+W

As, the container is insulted, thus q=0
Hence, ΔU=W=506.625J505 J

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